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Base catalysis is ineffective inconverting a hemiacetal to an acetal.

T1 - Synthesis of the E ring segment of ciguatoxin CTX3C via the negishi coupling of cyclic ketene acetal triflates

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so long as the conditions do not lead to hydrolysis of the acetal

Press release by the CNRS concerning our collaborative article in Angewandte Chemie, International Edition, titled: "Radical Copolymerization of Vinyl Ethers and Cyclic Ketene Acetals as a Versatile Platform to Design Functional Polyesters"

A Structurally Diagnostic Ion/Molecule Reaction for Cyclic Acetals and Ketals in the Gas Phase

Organic chemistry: “Amino acid and polypeptide synthesis”. Amino acid synthesis--Gabriel synthesis; synthesis. degradation. Polypeptide synthesis-- () and () amino-protecting groups; protection of the terminus via ester formation; DCC () -activating reagent. An example of calculating and charge at a specific pH for a long polypeptide

Cyclic acetal formation - ChemTube3D

Organic chemistry: “Carbohydrates”. Carbohydrates (sugars). D vs. L sugars; . Ring formation; projections; vs. ; vs. . . Glycosides (sugar ). Attack of acetone on sugar units to form cyclic

However, if the aldehyde functionality is first protected as an acetalfunction, the Grignard can be prepared quite nicely, and the protected Grignardreagent can then be used for whatever synthetic purpose may be desired.

Chemistry of Cyclic Acetals – School of Pharmacy

If the aldehyde functionality were notprotected, this Grignard reagent could not be formed in a synthetically usefulmanner, because it would quickly react with a molecule of the aldehyde.

In particular, the equilibrium for the formation of an aldehyde cyclic acetalis now favorable to the acetal, whereas it was not in the case of an acylicacetal.

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  • Carbohydrate cyclic acetal formation and migration

    In nature the most stable glucose exists as a cyclic hemiacetal and maltose is an acetal made from two glucose units.

  • Synthesis and characterization of cyclic acetal based ..

    A simple procedure for the formation of acetals of diaryl ketones has also been ...

  • Cyclic acetal synthesis | quibaygopinarlacoovetaparve

    Acyclic and cyclic acetals of various carbonyl compounds were obtained in excellent yields in ..

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Synthesis and properties of novel gels based on cyclic acetal

Julien delivered three lectures (incl. one as invited speaker) titled "Nitroxide-Mediated Radical Ring-Opening Copolymerization: A Single Cyclic Ketene Acetal Comonomer to Control the Polymerization of Methacrylates and to Confer Degradability", "Conjugation and Bioconjugation from α-Functional Polymers Obtained by Nitroxide-Mediated Polymerization (NMP) Initiated by N-Hydroxysuccinimidyl- or Azlactone-Functionalized Alkoxyamines" and "The Drug-Initiated Method: a Convenient Approach for the Synthesis of Efficient Polymer Prodrug Nanoparticles" at the International Chemical Congress of the Pacific Basin Societies (Pacifichem 2015), Honoluu, Hawai, USA.

In synthesis, an acetal can be used to protect a functional group

Megan's paper (collaboration with Brent Sumerlin's group) titled "Radical Ring-Opening Copolymerization of Cyclic Ketene Acetals and Maleimides Affords Homogeneous Incorporation of Degradable Units" is accepted in ACS Macro Letters. Congrats!

Cyclic acetal synthesis | BrainyResort

Our collaborative paper (with Didier Gigmes and Didier Letourneur's groups) titled "Radical Copolymerization of Vinyl Ethers and Cyclic Ketene Acetals as a Versatile Platform to Design Functional Polyesters" is accepted in Angew. Chem., Int. Ed. Congrats to all!

Rearrangement of the cyclic acetal isomers did ..

Johanna delivered a lecture titled "Radical Copolymerization of Vinyl Ethers and Cyclic Ketene Acetals: a New Platform to Challenge Traditional Polyesters for Biomedical Applications" at the SFNano 2017 meeting, Bordeaux, France. Bravo !


A way to remove water is to use an orthoester as a source of alcohol; water produced along with the acetal product is used up in hydrolysing the orthoester and producing more alcohol to be used in the reaction.

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