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Inesi."Electrogenerated Cyanomethyl Anion in Organic Synthesis.

Inesi."An Electrochemical Alternative Strategy to the Synthesis of ß-Lactams Part 3.

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Synthesis of Oxazolidine-2,4-diones";

Academic Papers ; Synthesis of Asymmetrically Arranged Dendrimers with a Carbazole Dendron and a Phenylazomethine Dendron ; Macromolecules(ACS) ; ; ; No.37/P.5531-5537 ; 2004



Assembly of A Porphyrin Array via the Molecular Recognition Approach: Synthesis and Properties of a Cyclic Zinc(Ⅱ) Porphyrin TrimerBased on Coordination and Hydrogen Bonding ; Inorg.

(eds) Novel Trends in Electroorganic Synthesis.

Inesi."An Electrochemical Alternative Strategy to the Synthesis of ß-Lactams.

"The Reaction of Acetylenic Amines with Tetraethylammonium Carbonate and Hydrogen Carbonate; Synthesis of 5-Methylene-1,3-oxazolidin-2-ones";

■Synthesis of 3,3,6,6-Tetraaryl-1,2-Dioxanes via TiO2-CatalyzedPhotooxygenationof 1,1-Diarylethenes in the Presence of Mg(ClO4)2, Maeda, H.; Miyamoto,H.; Mizuno, K. 2004, ,462-463.

Synthesis of 5-methylene-1,3-oxazolidin-2-ones";

Verdecchia."A New Approach to the Synthesis of Highly Substituted 3-Pyrrolin-2-ones";

Therefore, the use of anodic oxidation reactions to complement existing methodology can open entirely new strategies for the synthesis of complex molecules.

■Synthesis and Reactivity of New 1,4-Bis(alkylthio)-3,6-diarylthieno[3,4-]thiophene Derivatives, N. Matsumura, H. Tanaka, Y. Yagyu,K. Mizuno, H. Inoue, K. Takada, M. Yasui, and F. Iwasaki, ,63,163-168 (1998).

Inesi."An Electrochemical Alternative Strategy to the Synthesis of ß-Lactams.
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  • Inesi."Electrogenerated Cyanomethyl Anion in Organic Synthesis.

    Rossi."Electrochemical-Mediated Cyclization of 2-Alkynylanilines: A Clean and Safe Synthesis of Indole Derivatives";

  • Synthesis of Oxazolidine-2,4-diones";

    Inesi."Electrochemically Induced Aza-Henry Reaction: A New Mild, and Clean Synthesis of alpha-Nitroamines";

  • Synthesis of 5-methylene-1,3-oxazolidin-2-ones";

    Author: (book) Novel Trends in Electroorganic Synthesis, 1997. Contributor articles to science publications.

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Rossi."Tetraalkyl Ammonium Carbonates in Organic Synthesis";

For this reason, this review will highlight a number of anodic reactions in order to provide synthetic chemists with an overview of the types of transformations that are available for use in the future.

Inesi."The Electrogenerated Cyanomethyl Anion in Organic Synthesis";

"C-1 Reactivity of 2,3-Epoxy Alcohols via Oxirane Opening with Metal Halides: Applications and Synthesis of Naturally Occurring 2,3-Octanediol, Muricatacin, 3-Octanol and 4-Dodecanolide";

Rossi."Tetraalkyl Ammonium Carbonates in Organic Synthesis";

■Synthesis and Photochemical Properties of 2,2'-Silaspirobiindan andRelated Compounds, Y. Inoue, A. Sugimoto, and K. Mizuno, , 2000, 528-529.


This feeling is exacerbated by summaries of electrochemical reactions that describe a variety of reaction setups and electrochemical equipment that are not common to most synthetic laboratories.

New Synthesis of Chiral Oxazolidin-2-ones";


Rossi."New Synthesis of Oxazolidin-2-ones";

Recent trends in the synthesis of organo-fluorine compounds using the conventional selective electrochemicalfluorination (SEF) route as well as other novel synthetic approaches are presented. In the conventional SEF route,fluorinations of the active methylene group in the side chain as well as unsaturated alkenes have been achieved. Inthe case of heterocycles, nuclear fluorination is the predominant process. In aromatic compounds, nuclearsubstitution as well as addition proceeds simultaneously, leading to the formation of a mixture of products. Theinfluence of solvents, supporting electrolytes and adsorption on product yield and selectivity has also been evaluatedin recent studies. DME is found to be a superior solvent for the above processes. In the SEF process itself, redoxmediators have been employed to minimize passivation and achieve better current efficiencies. Nitrogen basescontaining perfluoro alkyl unit have been synthesized using redox catalysts as mediators and trifluoromethylationwas achieved by the sacrificial anode technique. The introduction of the trimethyl silyl (TMS) group into the ACF3moiety to form very reactive ACF2–TMS synthon, leads to the synthesis of interesting organic molecules. A briefsummary of important biologically active fluoro organic molecules that have been prepared by the electrochemicalroute is also provided.

New Synthesis of Chiral Oxazolidin-2-ones";

and (2004)Current approaches to the electrochemical synthesis of organo-fluorine compounds. Journal of Applied Electrochemistry, 34 (4). pp. 357-369. ISSN 0021-891X

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