Call us toll-free

IR peaks for Cis-4-Cyclohexene-1,2-Dicarboxylic Acid Anhydride.

of 3-sulfolene and maleic anhydride in production of 4-cyclohexene-cis-1,2, dicarboxylic anhydride ..

Approximate price


275 Words


cis-4-cyclohexene-1,2-dicarboxylic anhydride -- …

Ring-opening copolymerization of cyclohexene oxide with alicyclic anhydrides containing different ring strain (succinic anhydride, cyclopropane-1,2-dicarboxylic acid anhydride, and phthalic anhydride) was performed applying metal salen chloride complexes, (salen)MCl (M = Al, Cr, Co; salen = -bis(3,5-di--butylsalicylidene)diimine) with different metals and ligand–diimine backbones. While some of the bulk copolymerizations afforded poly(ester--ether)s, all solution polymerizations produced perfect alternating copolymers. The chromium catalysts performed best while the aluminum catalysts were the least active ones. For each metal, the salophen complexes yielded the best performing catalyst. A variety of cocatalysts have been employed: bis(triphenylphosphoranylidene)ammonium chloride, -heterocyclic nucleophiles including 4-(dimethylamino)pyridine, -methylimidazole, and 1,5,7-triazabicyclododecene and the phosphines trimesitylphosphine, tris(2,4,6-trimethoxyphenyl)phosphine, tricyclohexylphosphine to triphenylphsophine. Of all cocatalysts, bis(triphenylphosphoranylidene)ammonium chloride was found to be the most efficient cocatalyst in combination with salophenCrCl for the copolymerization of cyclohexene oxide with phthalic anhydride, and 1 equiv was enough to reach optimum activity. -Heterocyclic nucleophiles showed the lowest activity. Of the three anhydrides used, phthalic anhydride is the most reactive giving the highest conversions and the highest molecular weight products.

The objective of this lab is to prepare 4-cyclohexene-cis-1,2-dicarboxylic anhydride ..
Photo provided by Flickr

Goswami, A.; Kissick, T. P. Enzymatic Desymmetrization of Dimethyl Cylcohex-4-ene-cis-1,2-dicarboxylate to (1S,2R)-2-(Methoxycarbonyl)cyclohex-4-ene-1-carboxylic Acid. Org. Process Res. Dev. 2009, 13 (3), 483-488.Solano, D. M.; Hoyos, P.; Hernáiz, M. J.; Alcántara, A. R.; Sánchez-Montero, J. M. Industrial biotransformations in the synthesis of building blocks leading to enantiopure drugs. Bioresour. Technol. 2012, 115, 196-207.Su?ss, P.; Illner, S.; von Langermann, J.; Borchert, S.; Bornscheuer, U. T.; Wardenga, R.; Kragl, U. Scale-Up of a Recombinant Pig Liver Esterase-Catalyzed Desymmetrization of Dimethyl Cyclohex-4-ene-cis-1,2-dicarboxylate. Org. Process Res. Dev. 2014, 18 (7), 897-903.

Diels-Alder Reaction Flashcards | Quizlet

cis-1,2,3,6-Tetrahydrophthalic acid anhydride cis-4-Cyclohexene-1,2-dicarboxylic acid anhydride cis-4-Cyclohexene-1,2-dicarboxylic anhydride
Photo provided by Flickr

Goswami, A.; Kissick, T. P. Enzymatic Desymmetrization of Dimethyl Cylcohex-4-ene-cis-1,2-dicarboxylate to (1S,2R)-2-(Methoxycarbonyl)cyclohex-4-ene-1-carboxylic Acid. Org. Process Res. Dev. 2009, 13 (3), 483-488.

Start studying Diels-Alder Reaction

Linear polyesters of diethylene glycol with cis-and trans-4-cyclohexene-1,2-dicarboxylic acid. Synthesis, characterization and NMR structural study
Photo provided by Flickr

View Lab Report - Formal4_S14 from CHEMISTRY 26600 at Purdue. Diels-Alder Reaction: 4-Cyclohexene-cis-1,2-dicarboxylic Acid Anhydride Martin Gomez and …
Photo provided by Flickr

Order now
  • Organic Synthesis at VWR VWR has All You Need for Organic Synthesis


  • cis-1,2,3,6-Tetrahydrophthalic anhydride 95% | Sigma-Aldrich

    Structure, properties, spectra, suppliers and links for: 4-Cyclohexene-1,2-dicarboxylic acid, cis-.

  • Lab report #4: Diels-Alder Reaction - Google Docs

    Sigma-Aldrich offers Aldrich-136891, cis-1,2,3,6-Tetrahydrophthalic anhydride for your research needs

Order now
  • Kim

    "I have always been impressed by the quick turnaround and your thoroughness. Easily the most professional essay writing service on the web."

  • Paul

    "Your assistance and the first class service is much appreciated. My essay reads so well and without your help I'm sure I would have been marked down again on grammar and syntax."

  • Ellen

    "Thanks again for your excellent work with my assignments. No doubts you're true experts at what you do and very approachable."

  • Joyce

    "Very professional, cheap and friendly service. Thanks for writing two important essays for me, I wouldn't have written it myself because of the tight deadline."

  • Albert

    "Thanks for your cautious eye, attention to detail and overall superb service. Thanks to you, now I am confident that I can submit my term paper on time."

  • Mary

    "Thank you for the GREAT work you have done. Just wanted to tell that I'm very happy with my essay and will get back with more assignments soon."

Ready to tackle your homework?

Place an order