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Facile Microwave-Assisted Synthesis of Lanthanide …
Upconversion nanoparticles can emit ultraviolet/visible/near-infrared light under near-infrared excitation, also known as anti-Stokes emission. This unique optical property precludes background fluorescence and light scattering from biological materials, which opens up new avenues for optical bio-applications, such as bioimaging, photodynamic treatment, drug delivery, etc. In order to achieve better application performance, highly efficient lanthanide upconversion nanoparticles is desired in many cases. Generally, the quality of the upconversion nanoparticles is always related to their synthetic methods. In this review, we will focus primarily on the various synthetic procedures for the upconversion nanoparticles. Moreover, several effective ways to obtain high luminescence efficiency are summarized.
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Synthesis of lanthanide carbonates - ScienceDirect
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Synthesis Of Lanthanide And Actinide Compounds
Hydrogen sulfide (H2S) is now recognized as an important gaseous transmitter that is involved in a variety of biological processes. Here, we report the design and synthesis of a luminescent lanthanide biosensor for H2S, LP2-Cu(II)-Ln(III), a heterobinuclear metal complex that uses Cu(II) decomplexation to control millisecond-scale-lifetime-Tb(III)- or Eu(III)-emission intensity. LP2-Cu(II)-Ln(III) responded rapidly, selectively, and with high sensitivity to aqueous H2S. The probe’s potential for biological applications was verified by measuring the H2S generated by the slow-releasing chemical-sulfide-donor GYY4147, by cystathionine γ-lyase (CSE), and by Na2S-stimulated HeLa cells.
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